Refrigerants are chemical compounds that are alternately compressed and condensed into a liquid and then permitted to expand into a vapour or gas as they are pumped through the mechanical refrigeration system to cycle. Ideal Refrigerant must have low specific heat and high latent heat. Refrigerants evaporate at much lower temperatures than water, which permits them to extract heat at a more rapid rate.
Most refrigerants used are substances obtained by chemical synthesis and consequently have ideal properties for the specific purpose. Many of these, however, have negative effects on the environment, in particular they tend to destroy the ozone layer (i.e. have a high ODP, Ozone Depletion Potential) or directly contribute to the greenhouse effect (i.e. have a high GWP, Global Warming Potential). Types of refrigerants include CFC (chlorofluorocarbon, high ODP),HCFC (hydrochlorofluorocarbon, low ODP, high GWP), HFC (hydrofluorocarbon, zero ODP, high GWP), HFO (hydrofluoroolefin, zero ODP, low GWP), HC (hydrocarbons, zero ODP, negligible GWP) and natural refrigerants Ammonia & CO2 have zero ODP, zero or negligible GWP. Environment friendly coolants such as R–290, R–600A etc are being used.