Significant figures
Structure of Matter > Chemical Calculation

A quantity can never be measured exactly. Therefore, every measurement includes some uncertainty.

The acceptance of uncertainty depends upon the measuring device used. When we buy a piece of cloth, a scale that measures in 0.1cm increments is perfectly acceptable. It tells us that the length is, for example, 50 ± 0.1 cm. The term “± 0.1cm” expresses the uncertainty in the measurement: the length of the cloth between 49.9 and 50.1cm. The greater the number of digits in a measurement represents that the value has more certainty.

The uncertainty can be expressed with “±” sign, but generally we ignore the sign and assume an uncertainty of one unit in the right most digit. Both the certain and uncertain digits of a measurement are called significant figures. Finally, greater the number of significant figures in a measurement, greater is the certainty.

The number of significant figures can be defined as the number of digits necessary to express the results of a measurement consistent with the measured precision. The number of significant figures includes all the digits that are known and the first uncertain one.

The digit ‘zero’ is a significant figure under following conditions:

  • If it is not the first digit of a number.
  • If it is not used to place the decimal.
    E.g: In 0.0257, the digit zero between decimal and 2 is used only to place the decimal and is not a significant figure.
  • If it falls between two other nonzero integer.
    E.g: In 45,078, zero is a significant figure.

Worked Out Example

How many significant figure does each of the following numbers have?
(a) 4570 (b) 0.007 (c) 5000.0 (d) 0.04785 (e) 200.07 (f) 5.40 × 108

Solution:

Number Significant Figure
(a) 4570 4
(b) 0.007 1
(c) 5000.0 5
(d) 0.04785 4
(e) 200.07 5
(f) 5.40 × 108 3

Rounding off:

  • If the digit following the last significant figure is greater than 5, the number is rounded to next higher digit.
    E.g: 8.38 = 8.4
  • If the digit following the last significant figure is less than 5, the number is rounded off to the present value of the last significant figure.
    E.g: 8.53 = 8.5
  • If the last digit is 5, the number is rounded off to the nearest even digit.
    E.g: 7.75 = 7.8
    6.45 = 6.4
    9.55 = 9.6

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