Fourth transition series (or) 6d-series
Metals & Non-Metals > Transition Metals
Element Symbol At. No. Electronic configuration
Actinium Ac 89 6d–orbitals are filled up [Rn] 6d17s2
Rutherfordium Rf 104 [Rn] 5f146d27s2
Hahnium Ha 105 [Rn] 5f146d37s2
Seaborgium Sg 106 [Rn] 5f146d47s2
Bohrium Bh 107 [Rn] 5f146d57s2
Hassium Hs 108 [Rn] 5f146d67s2
Meitnerium Mt 109 [Rn] 5f146d77s2
Ununnilium Uun 110 [Rn] 5f146d87s2
Unununium Uuu 111 [Rn] 5f146d97s2
Unubium Uub 112 [Rn] 5f146d107s2

6d–series consists of elements Ac (atomic number 89) and those beyond Rutherfordium/Kurchatovium (atomic number 104). These elements lie in the seventh period. This period is still incomplete. At present this series consist of Ac89, Ku104, Ha105 and Unh106 (four elements). These elements involve the gradual filling of 6d orbitals. In between Ac89 and Ku104 there are 14 elements viz. Th90 to Lw103 which are called actinides or actinones. These 14 elements involve the progressive filling of 5f orbitals and hence do not belong to 6d–series. Thus at Lw103 5f orbitals are completely–filled. Consequently at Ac89, 5f orbitals are vacant (5f0 configuration) while in the remaining elements viz. Ku104, Ha105 and Unh106 (three elements), 5f orbitals are completely–filled (5f14 configuration).

Complete and valence–shell configurations of the atoms of 6d–series elements can be written as follows. Here [Rn]86=2, 8, 18, 32, 18, 8 (six shells).

Complete configuration = [Rn]86 5f06d1–47s2; which is otherwise written as 2, 8, 18, 32, 5s2p6d10f 06s2p6d1–4, 7s2 (7shells) valence–shell configuration =
5f0–14 6d1–47s2

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